Charge Transfer Interactions between Isonicotinic Acid Hydrazide and Cupric Ions

Synthesis and structural studies of complexes of Cu, Co, Ni and Zn with isonicotinic acid hydrazide and isonicotinic acid (1-naphthylmethylene)hydrazide

Eight new complexes of Cu(II), Co(II), Ni(II) and Zn(II) with isonicotinic acid hydrazide (isoniazid, (INH)) and isonicotinic acid (1-naphthylmethylene)hydrazide (INNMH), having the formula of the type [M(INH)(ac)2] or [M(INNMH)(ac)2] (M = Co(II), Ni(II) and Zn(II)) and [Cu(INH)(ac)2]2, [Cu(INNMH)(ac)2]2, were synthesized and characterized. All complexes were characterized based on elemental an...

Two nd-zn and sm-zn isonicotinic/nicotinic Acid complexes.

The 4f-3d heterometallic complexes [Nd(L)3(H2O)2]2(ZnCl4)3n • 4nH2O (1) (L = isonicotinic acid) and [Sm(L')3(H2O)2]2(ZnCl4)n • 2nH2O (2) (L' = nicotinic acid) have been obtained by hydrothermal reactions and structurally characterized by X-ray single-crystal diffractions. Both complexes feature an infinite 1-D polycationic chain-like structure. Photoluminescent investigations reveal that both c...

Studies on the Charge-Transfer Interaction Between Tamoxifen Citrate and Chloranilic Acid

      The complex formed as a consequence of the interaction between the electron-acceptor P-chloranilic acid and an electron donor tamoxifen citrate was employed in the assay of the drug in pure powder and tablets. Chloranilic acid was found to form a charge-transfer complex in a 1:1 stoichiometric ratio, with tamoxifen citrate. The wavelength of maximum absorption for the complex was found to...

Isonicotinic Acid Hydrazide

Charge-transfer interactions between nucleobases and metal ions: ESR and optical absorption studies.

The charge-transfer interaction of different nucleobases with Cu2+ has been investigated by means of ESR and optical absorption studies. It could be shown that cytosine forms the strongest complex. The greatest reduction of Cu2+ (that is, spin concentration) was obtained, however, with adenine. Based on these results the following order for the electron donor strength of the nucleo­ bases has b...